Gypsum plaster is a cementitious finishing material made by heating gypsum rock to drive off most of its chemically bound water, producing a powder that, when mixed with water, sets quickly into a smooth, hard, fire-resistant surface for interior walls and ceilings. Known since antiquity, notably for the plaster of Paris named for the extensive gypsum deposits beneath that city, it became a standard interior finish material across much of the world because it can be applied over lath, masonry or modern gypsum board and worked into smooth or decorative ornamental surfaces such as cornices and ceiling roses. Its fire resistance comes from the water chemically bound in its crystal structure, which is driven off as steam when the material is exposed to flame, slowing heat transfer through the wall or ceiling assembly.
Sources
Wikipedia
Wikimedia FoundationWikipedia: Gypsum, plaster of Paris section, https://en.wikipedia.org/wiki/GypsumQuote, Wikipedia: Gypsum, plaster of Paris section, https://en.wikipedia.org/wiki/Gypsum
Upon adding water, after a few dozen minutes, plaster of Paris becomes regular gypsum (dihydrate) again, causing the material to harden or "set" in ways that are useful for casting and construction.
View the Source Encyclopedia Britannica
Encyclopedia Britannica, Inc.Britannica: Gypsum, opening paragraph, on the fibrous satin spar variety, https://www.britannica.com/science/gypsumQuote, Britannica: Gypsum, opening paragraph, on the fibrous satin spar variety, https://www.britannica.com/science/gypsum
The fibrous massive variety has a silky lustre and is called satin spar; it is translucent and opalescent and is valued for ornaments and jewelry.
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